주식회사 백강방수, 물질안전보건자료(Material Safety Data Sheet)

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

A Product name            Additive for cement, concrete

B. Use of substance        Cement, Concrete Waterproof agent

C. Supplier

Head office          Baekkang Waterproof Co.,Ltd.

Address             3rd floor, 450 Yeoksam-ro, Gangnam-gu, Seoul, Republic of Korea

 (06201, Sewon Building)

Emergency telephone number        Telephone : 02-582-6007  Mobile number: 010-3910-6012

2. HAZARDS IDENTIFICATION

A GHS Classification    Metal Corrosive Substance : Category 1

Skin/Eye Corrosion : Category 1

Specific target organ toxicity (Single Exposure): Category 1

Target organ: Respirator

B. Label elements including precautionary statements

Symbols

Signal words                             Danger

Hazard-Risk Statement                   H290 May be corrosive to metals

.                                       H314 Causes severe skin burns and eye damage.

H370 Can cause respiratory damage

Precautionary Statement Prevention

Prevention                           P234 Store in original container only.

P260 Do not inhale dust, fume, mist, gas, vapor, spray.

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wash … thoroughly after handling.

Response         P301+P330+P331 IF SWALLOWED: Wash thoroughly with water, do not induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P310 Get medical advice/attention immediately.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

Lenses, if present and easy to do: Continue rinsing.

P307+P311 IF EXPOSURED: Call a POISON CENTER/doctor

P390 Absorb spillage to prevent material damage.

Storage            P405 Store locked up.

P406 It is a metal corrosive substance and should be stored in a corrosion-resistant container (as specified by the manufacturer or the competent authority). Disposal

Disposal           P501 Dispose of contents/container to... in accordance with

local/regional/national/international regulations (to be specified).

C. Other Hazard-Risk which are not included in the classification criteria (e.g. dust explosion hazard)

Health                            3

Fire                               0 

Reactivity                          0

3. Composition/Information on ingredients

Ingredients                        CAS No           EINECS No             Content (%)

Sodium hydroxide                  1310-73-2   .      215-185-5              10 - 20

Sulfur                             7704-34-9         231-722-6              15 - 25

Water                             7732-18-5         231-791-2              55 - 75

4. First aid measures

A. Eye contact         Seek medical attention. Wash affected eyes for at least 15 minutes under running water with eyelids held open.

B. Skin contact            Wash thoroughly with soap and water.

C. Inhalation                      Remove the affected individual into fresh air and keep the person calm. Seek medical attention.

Give artificial respiration if do not breathe.

D. Ingestion                     If unconscious, do not feed anything to mouth. Wash mouth with water.

Seek medical attention.

E Indication of immediate medical   Have the medical personnel know about the material

attention notes for physician       and take protective measures.

 

5. Fire Fighting measures

A. Combustion characteristic          Non- flammable below 250°C

B. Suitable extinguishing media     Water spray, dry extinguishing media, carbon dioxide, foam

C. Products of Combustion              No data

D. Protective equipment for fire-fighting  Wear air-breathing apparatus if necessary.

 

6. Accidental release measures

A. Personal precautions            Use personal protective clothing

B. Environmental precautions       Do not discharge into drains surface waters, ground water.

C. Cleanup                        Store in appropriate container for disposal.

 

7. Handling and storage

A. Handling                       Wear protective gloves, protective clothing, eye protection.

 and face shield.                   Wash thoroughly after handling

                                  Do not eat, drink or smoke when using the product.

B.  Storage                        Keep container tightly closed,

Store in lockable storage area

It is a metal corrosive substance and should be kept in a corrosion resistant container.

 

8. Exposure controls / personal protection

A. Control parameters. (e.g. occupational exposure limit values or biological limit values.)

Domestic regulation             Sodium hydroxide TWA 2mg/m. Ceiling

AOGIH                   Sodium hydroxide TWA 2mg/m, Ceiling

B. Engineering controls      Emergency shower, air exhauster

C. Personal protection

Eyes                   Goggles

Body                   Lab coat

Hands                  Gloves

Respiratory              Approved cartridge attached air respirator

Lab coat      

Hands                  Gloves

Respiratory              Approved cartridge attached air

 

9. Physical and chemical properties

A. Appearance                   Liquid at 20°

B. Flash point("C)                 Non flammable below 250°C

C. Auto-ignition temperature("C) :  Not ignited below 200°C

D. PH                            >12.0 (@20°C)  Sample : H2O=1:10 (V/V)

E. Specific gravity                 1.20-1.30 at 20°C

F. Solubility                       Soluble

G. Explosion hazard               Not dangerous *UN TDG test & cnitena-Test E3

H. Oxidation hazard               Not dangerous *UN TDG test & cnitena-Test O2

I. Viscosity                        No data

J. Vapor pressure                  No data

K. bp("C)                          >98°C

L. mp/fp(°C)                       No data

M. Decomposition temp.(°C)        No data

N. Partition coefficient              No data

(n-octanol/water)

O. Evaporation rate                 No data

P. Upper/lower explosive limits      No data

 

10. Stability and reactivity

A. Chemical stability                      Stable under normal storage condition

B. Incompatibility with various substances  Avoid inhalation of mist gas and steam.

                                           Avoid metals and acids

C. Possibility of hazardous reactions        Stable under normal storage condition

   D. Hazardous decomposition products     Sulfur oxide

 

11. Toxicological information

A. Information on the likely routes of exposure

Inhalation                             Not available

Ingestion                             Not available

Serious Eye damage                   Corrosive (Sodium hydroxide) * from US NLM /ECHA

Respiratory sensitization                Not available

Skin sensitization                      Not available

Carcinogenicity                        Not available

Reproduction toxicity                   Not available

Eye                                   Not available

Skin                                  Not available

B. Delayed and immediate effects and also chronic effects from short- and long-term exposure

Acute toxicity

Ora                                  rat LD50 : 2,000 mg/kg * from US NLM /ECHA

Skin                                 rabbit LD50 : No data

Inhalation                            rat LC50 : No data

Skin imitation                        Corrosive (Sodium hydroxide) * from US NLM /ECHA

Serious Eye damage                  Corrosive (Sodium hydroxide) * from US NLM /ECHA

Respiratory sensitization              Not available

Skin sensitization                    Not available

Carcinogenicity                     Not available

Reproduction toxicity                Not available

C. Numerical measure of toxicity(such as   Not available

acute toxicity estimates)

12. Ecological information

A. Ecotoxicity

Fish                                  LC 50 : 100mg/L, 96h

Orustacean                           Not available

Algae                                Not available

B. Persistence and degradability            Not available

C. Bio accumulative potential               Not available

D. Mobility in soil                         Not available

E. Other adverse effect                    Not available

 

13. Disposal considerations

A. Waste information                  Waste must be disposed of in accordance with federal, 

state and local environmental control regulations.

B. Container disposal           Dispose of in a licensed facility. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers

 

14. Transport information

A. UN number                      Number: 1760    Class: 8      Packing Group: II

B. UN proper shipping name         Corrosive liquid, n.o.s (contains sodium hydroxide)

C. Transport Hazard class(es)         No data

D. Packing group                    No data

E Marine pollutant                   No data

 

15. Regulatory information

A. Industrial safety and Health Act

- US OSHA hazards (GHS)           Metal corrosive substance Category1

Skin/eye corrosive substance Category 1

Specific organ target toxicity-Category 1

- Managed substance               Sodium hydroxide

- Substance subject to special health check  Not applicable

- Toxic substances to be permitted    Not applicable

B. Toxic Chemical Control Act          Toxic substance

C. Dangerous Material Safety Control Act  Not dangerous

D. Other requirements in domestic and   No data

       other countries

 

16. Other information

A. Information on preparation

Hazard-Risk Statement, GHS Classification (Korean MSDS Test Certificate (Report No. 2015-03-002137), US NUM Physical properties (Korean MSDS Test Certificate) UN Transport information (Korean MSDS Test Certificate)

Toxicological and Ecological information (OECD, SIDS, ECHA US NLM, HSDB, IARC, CCRIS, JP NITE)

-       Abbreviation and Website

ECHA: European chemical agency, http://echa.europa.eu/

US NLM U.S. National Library of Medicine, http://chem.sis.nlm.nih.gov/chemidplus/

HSDB: U.S. Hazardous Substances Data Bank http://toxnet.nlm.nih.gov/

CORIS: U.S. Chemical Carcinogenesis Research Information System http://toxnet.nlm.nih.gov/

IARG International Agency for Research on Cancer, http://monographs.iarc.fr/

JP NTE: Japan National Institute of Technology and Evaluation, http://www.safe.nite.go.jp/

B. Issuing date                          2015.12.31

C. Revision date

D. Revision number                          0

E. Others

- Risk test and Classification

Korean MSDS Testing Laboratory

Website: www.msdskorea.com Telephone: 031.337.3701 / 031.337.3702

Address: 12, Iwon-ro, Idong-eup, Cheoin-gu, Yongin-si, Gyeonggi-do, Republic of Korea